Photochemistry and Electron Transfer Studies
When a molecule absorbs a photon, it enters an electronically excited state where its chemical behavior can change dramatically — bonds weaken, charges shift, and protons migrate in ways that simply don't occur at equilibrium. Photochemistry and electron transfer research maps these fleeting transformations at the molecular level, tracing how excited-state proton transfer, intramolecular charge redistribution, and the surrounding solvent's response collectively determine what a molecule does with the energy it has absorbed. Understanding these dynamics matters practically because they govern the efficiency of technologies like luminescent solar concentrators and organic optoelectronic devices, where controlling where charge goes — and how quickly — is the difference between useful work and wasted heat. Active questions center on how hydrogen bonding networks mediate ultrafast proton and charge motion, and on designing molecular architectures that achieve high fluorescence quantum yields while directing energy precisely where it is needed.
- Works
- 85,435
- Total citations
- 1,808,421
- Keywords
- Excited-State Proton TransferIntramolecular Charge TransferSolvation DynamicsLuminescent Solar ConcentratorsHydrogen BondingFluorescence Quantum Yields
Top papers in Photochemistry and Electron Transfer Studies
Ordered by total citation count.
- Universal Solvation Model Based on Solute Electron Density and on a Continuum Model of the Solvent Defined by the Bulk Dielectric Constant and Atomic Surface Tensions↗ 17,678OA
- Quantum Mechanical Continuum Solvation Models↗ 16,635
- Critical Review of rate constants for reactions of hydrated electrons, hydrogen atoms and hydroxyl radicals (⋅OH/⋅O− in Aqueous Solution↗ 12,212
- Quantum Calculation of Molecular Energies and Energy Gradients in Solution by a Conductor Solvent Model↗ 10,075
- COSMO: a new approach to dielectric screening in solvents with explicit expressions for the screening energy and its gradient↗ 9,474
- Electrostatic interaction of a solute with a continuum. A direct utilizaion of AB initio molecular potentials for the prevision of solvent effects↗ 8,923
- Zwischenmolekulare Energiewanderung und Fluoreszenz↗ 8,214OA
- Electron transfers in chemistry and biology↗ 8,037
- Energies, structures, and electronic properties of molecules in solution with the C‐PCM solvation model↗ 7,995
- The Temperature Dependence of Relaxation Mechanisms in Amorphous Polymers and Other Glass-forming Liquids↗ 7,943
- On the Theory of Oxidation-Reduction Reactions Involving Electron Transfer. I↗ 6,023
- Solvatochromic Dyes as Solvent Polarity Indicators↗ 5,473
Active researchers
Top authors in this area, ranked by h-index.