Electrostatics and Colloid Interactions
When polymers carry electrical charges along their backbone, they interact with surrounding ions and solvent in ways that are difficult to predict and surprisingly rich in behavior. Polyelectrolyte research sits at the intersection of electrostatics and soft matter physics, using theory and simulation to understand how charged polymers arrange themselves in solution, how counterions condense onto their surface, and how thin electrical double layers govern forces between colloidal particles. These phenomena underpin everything from biological macromolecules like DNA and proteins to industrial applications in coatings, drug delivery, and water treatment. Active questions include how to accurately model ion-specific effects that classical mean-field theories miss, and how dielectric variations near charged interfaces reshape the electrokinetic behavior of particles in realistic, crowded environments.
- Works
- 48,003
- Total citations
- 921,089
- Keywords
- PolyelectrolytesElectrostaticsCounterion CondensationElectrokineticsDielectric ConstantSoft Matter Systems
Top papers in Electrostatics and Colloid Interactions
Ordered by total citation count.
- Particle mesh Ewald: An <i>N</i>⋅log(<i>N</i>) method for Ewald sums in large systems↗ 30,306OA
- High resolution two-dimensional electrophoresis of proteins.↗ 19,360OA
- Tricine-sodium dodecyl sulfate-polyacrylamide gel electrophoresis for the separation of proteins in the range from 1 to 100 kDa↗ 11,508
- Dispersion and Absorption in Dielectrics I. Alternating Current Characteristics↗ 9,882
- Adsorption Surface Area and Porosity↗ 9,515
- A well-behaved electrostatic potential based method using charge restraints for deriving atomic charges: the RESP model↗ 8,029
- Theory of simple liquids↗ 7,747
- Theory of self-assembly of hydrocarbon amphiphiles into micelles and bilayers↗ 5,094
- Dispersion of soluble matter in solvent flowing slowly through a tube↗ 5,050
- Diffusion, mass transfer in fluid systems↗ 4,964
- DISC ELECTROPHORESIS‐I BACKGROUND AND THEORY*↗ 4,577
- The Viscosity of Concentrated Suspensions and Solutions↗ 4,504
Active researchers
Top authors in this area, ranked by h-index.